Issue 12, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Biosynthesis of monocerin. Incorporation of 2H-, 13C-, and 18O-labelled acetates by Drechslera ravenelii

Fiona E. Scott,   Thomas J. Simpson,   Laird A. Trimble  and  John C. Vederas  

Abstract

Incorporation of 2H-, 13C-, 18O-labelled acetates into monocerin (1) by cultures of Drechslera revenelii and analysis of the enriched metabolites by 2H and 13C n.m.r. spectroscopy indicate a heptaketide origin; observation of 2H and 18O isotope shifts in the 13C n.m.r. spectrum allows the fate of acetate-drived hydrogen and oxygen on incorporation into monocerin to be followed and conclusions on the mechanism of formation of the fused furobenzopyrone ring system to be drawn.

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Article information

DOI
https://doi.org/10.1039/C39840000756
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 756-758

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Biosynthesis of monocerin. Incorporation of 2H-, 13C-, and 18O-labelled acetates by Drechslera ravenelii

F. E. Scott, T. J. Simpson, L. A. Trimble and J. C. Vederas, J. Chem. Soc., Chem. Commun., 1984, 756 DOI: 10.1039/C39840000756

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