Issue 10, 1984

Photochemically generated organometallic radicals as reducing agents

Abstract

Irradiation of metal–metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru3(CO)12, CpMo(CO)3Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order to demonstrate the utility of these photogenerated reducing agents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 632-633

Photochemically generated organometallic radicals as reducing agents

A. E. Stiegman, A. S. Goldman, D. B. Leslie and D. R. Tyler, J. Chem. Soc., Chem. Commun., 1984, 632 DOI: 10.1039/C39840000632

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