Electronic absorption spectra of a monodentate W(CO)5L intermediate have been recorded during the photoinitiated reaction of W(CO)5L with L = 1,4-diazabutadiene and 2,2′-bipyridine; the W(CO)5L species subsequently extrudes CO in a first order kinetic process to form W(CO)4L.
M. J. Schadt, N. J. Gresalfi and A. J. Lees, J. Chem. Soc., Chem. Commun., 1984, 506 DOI: 10.1039/C39840000506
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