Issue 8, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of a tetrahedral WC3 framework from a cyclic WC3(tungstenacyclobutadiene) system via attack on tungsten by nitrogen-doner ligands: X-ray study of W[C3Me2(But)][Me2N(CH2)2NMe2]Cl3

Melvyn Rowen Churchill,   Joseph W. Ziller,   Steven F. Pedersen  and  Richard R. Schrock  

Abstract

The tungstenacyclobutadiene complex W[C3Me2(But)]Cl3 reacts with Me2N(CH2)2 NMe2 to form the 1:1 adduct W[C3Me2(But)][Me2N(CH2)2 NMe2]Cl3; a single-crystal X-ray diffraction study of this product shows it to possess a ‘tungstenatetrahedrane’-like core with short W–C distances[2.040(7),2.115(7), 2.133(7)Å].

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Article information

DOI
https://doi.org/10.1039/C39840000485
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 485-486

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Formation of a tetrahedral WC3 framework from a cyclic WC3(tungstenacyclobutadiene) system via attack on tungsten by nitrogen-doner ligands: X-ray study of W[C3Me2(But)][Me2N(CH2)2NMe2]Cl3

M. R. Churchill, J. W. Ziller, S. F. Pedersen and R. R. Schrock, J. Chem. Soc., Chem. Commun., 1984, 485 DOI: 10.1039/C39840000485

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