Issue 21, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Room-temperature polymerisation of ethylene on a TiO2(anatase) surface; infrared spectroscopic evidence for an alkylidene–Ti4+ polymer end-group and for a ‘hydrogen-bonding’ type of interaction of CH bonds of the polymer chain with the oxide surface

Ferdos Al-Mashta,   Celso U. Davanzo  and  Norman Sheppard  

Abstract

An infrared spectroscopic study of the spontaneous polymerization of ethylene on a sulphate-containing TiO2(anatase) sample shows evidence for an alkylidene surface end-group of the polymer and for substantial perturbation of CH2 groups of the polymer chain by interaction with the oxide surface.

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Article information

DOI
https://doi.org/10.1039/C39830001258
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1258-1259

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Room-temperature polymerisation of ethylene on a TiO2(anatase) surface; infrared spectroscopic evidence for an alkylidene–Ti4+ polymer end-group and for a ‘hydrogen-bonding’ type of interaction of CH bonds of the polymer chain with the oxide surface

F. Al-Mashta, C. U. Davanzo and N. Sheppard, J. Chem. Soc., Chem. Commun., 1983, 1258 DOI: 10.1039/C39830001258

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