Issue 3, 1983

The use of 13C–{1H selective} nuclear Overhauser enhancement experiments in the determination of the structure of a highly crowded quinone–diazoalkane epoxide adduct

Abstract

Using heteronuclear nuclear Overhauser enhancement techniques the structure and conformation have been established for a highly crowded quinone–diazoalkane epoxide adduct, (3aS*,9S*,9aR*)-3,9a-dihydro-3,3,3′,3′,9a-pentamethylspiro-[9H-benz[f] indazole-9,2′-oxiran]-4(3aH)-one, formed from 2-methylnaphthoquinone and 2-diazopropane.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 107-108

The use of 13C–{1H selective} nuclear Overhauser enhancement experiments in the determination of the structure of a highly crowded quinone–diazoalkane epoxide adduct

M. F. Aldersley, F. M. Dean and B. E. Mann, J. Chem. Soc., Chem. Commun., 1983, 107 DOI: 10.1039/C39830000107

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