SCHEDULED MAINTENANCE
Cyclododecanone ws converted into the 20-membered cycloalkenes (11E) and (11EZ) and into (Z,E)-cycloeicosadec-5-en-1-one to illustrate a method for repetitive ring expansion based on the use of (phenylseleno)acetaldehyde and the siloxy-Cope rearrangement.
D. L. J. Clive, A. G. Angoh, S. C. Suri, S. N. Rao and C. G. Russell, J. Chem. Soc., Chem. Commun., 1982, 828 DOI: 10.1039/C39820000828
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