Issue 14, 1982

Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]

Abstract

The first metallabenzene,[O[graphic omitted]H)(CO)(PPh3)2] has been prepared from [Os(Co)(CS)(PPh3)3] and ethyen; X- ray crystal structure determination reveals a planar six-membered ring with no significant alternation of C–C bond lengths thus supporting the idea of electron delocalization within the ring.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 811-813

Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]

G. P. Elliott, W. R. Roper and J. M. Waters, J. Chem. Soc., Chem. Commun., 1982, 811 DOI: 10.1039/C39820000811

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