Issue 21, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Polynuclear tungsten-iron, -ruthenium and -osmium carbonyl complexes: crystal structures of [FeW2(µ3-C2R2)(CO)6(η-C5H5)2], [OsW2(µ3-C2R2)(CO)7-(η-C5H5)2](two isomers), and [Os3W(µ3-CR)(CO)11(η-C5H5)](R = C6H4Me-4)

Luigi Busetto,   Michael Green,   Judith A. K. Howard,   Bernd Hessner,   John C. Jeffery,   Rona M. Mills,   F. Gordon A. Stone  and  Peter Woodward  

Abstract

Reactions of polynuclear carbonyl complexes of iron, ruthenium, or osmium with [W[triple bond, length as m-dash]CR(CO)2(η-C5H5)](R = C6H4Me-4) afford several heteronuclear metal cluster compounds, and the structures of [FeW2(µ3-C2R2)(CO)6(η-C5H5)2], [Os3W(µ3-CR)(CO)11(η-C5H5)], and [OsW2(µ3-C2R2)(CO)7(η-C5H5)](two isomers) have been established by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39810001101
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1101-1103

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Polynuclear tungsten-iron, -ruthenium and -osmium carbonyl complexes: crystal structures of [FeW2(µ3-C2R2)(CO)6(η-C5H5)2], [OsW2(µ3-C2R2)(CO)7-(η-C5H5)2](two isomers), and [Os3W(µ3-CR)(CO)11(η-C5H5)](R = C6H4Me-4)

L. Busetto, M. Green, J. A. K. Howard, B. Hessner, J. C. Jeffery, R. M. Mills, F. G. A. Stone and P. Woodward, J. Chem. Soc., Chem. Commun., 1981, 1101 DOI: 10.1039/C39810001101

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