Issue 21, 1981

Synthesis and reactivity of bimetallic Au–Ag complexes. X-Ray structure of a chain polymer containing the moiety…(F5C6)2Au(µ-AgSC4H8)2Au(C6F5)2

Abstract

The 1 : 1 reaction between [Bu4N][Au(C6F5)2] and AgCIO4 in dichloromethane gives yellow solutions, from which solids of stoicheiometry Au(C6F5)AgL can be precipitated by the addition of O, N, S, or P-donors, L; and X-ray diffraction study for L = SC4H8 reveals [AuAg]2 rings linked by Au ⋯ Au interactions to form infinite metal-atom chains.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1097-1098

Synthesis and reactivity of bimetallic Au–Ag complexes. X-Ray structure of a chain polymer containing the moiety…(F5C6)2Au(µ-AgSC4H8)2Au(C6F5)2

R. Usón, A. Laguna, M. Laguna, P. G. Jones and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 1981, 1097 DOI: 10.1039/C39810001097

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