Iron(III) and manganese(III) porphyrins catalyse the oxygen transfer from iodosylbenzene to aromatic substrates to yield phenolic products; the resultant p-methoxyphenol or p-cresol exhibits a marked NIH shift.
C. K. Chang and F. Ebina, J. Chem. Soc., Chem. Commun., 1981, 778 DOI: 10.1039/C39810000778
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