SCHEDULED MAINTENANCE
Treatment with mercury(II) acetate of metal complexes of porphyrins bearing peripherally unsubstituted positions gives the corresponding mercurated derivatives; using the palladium–olefin reaction, this observation is exploited in the synthesis of coproporphyrin III tetramethyl ester (2), harderoporphyrin trimethyl ester (3), and isoharderoporphyrin trimethyl ester (4).
K. M. Smith and K. C. Langry, J. Chem. Soc., Chem. Commun., 1980, 217 DOI: 10.1039/C39800000217
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...