Metallation and alkylation (MeI) of the aldimines derived from various terpene methoxy amines and octanal1 produce, after hydrolysis, S(+)-2-methyloctanal in 11–75% enantiomeric excess.
A. I. Meyers, Z. Brich, G. W. Erickson and S. G. Traynor, J. Chem. Soc., Chem. Commun., 1979, 566 DOI: 10.1039/C39790000566
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