SCHEDULED MAINTENANCE
1-Methyltricyclo[3.2.1.02,7]octan-6-ones can be prepared in one step from the α′-enolates of αβ-cyclohexenones and isopropenyltriphenylphosphonium bromide; this reaction has been employed as the key step in a synthesis of trachyloban-19-oic acid from podocarpic acid.
R. M. Cory, Y. M. A. Naguib and M. H. Rasmussen, J. Chem. Soc., Chem. Commun., 1979, 504 DOI: 10.1039/C39790000504
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