An X-ray structure determination of the title compound has shown it to be a dimer involving a novel asymmetric Os2O2 bridge system; in solution the bridge breaks to give a pentaco-ordinate monomer [OsO2(O2C6H10)(C7H13N)].
B. A. Cartwright, W. P. Griffith, M. Schröder and A. C. Skapski, J. Chem. Soc., Chem. Commun., 1978, 853 DOI: 10.1039/C39780000853
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