SCHEDULED MAINTENANCE
A stable complex of the unstable intermediate, thioformaldehyde, results from reaction of the thioformyl complex [Os(CHS)Cl(CO)2(PPh3)2] with NaBH4; [Os(η2-CH2S)(CO)2(PPh3)2] forms methanethiolato-derivatives with acids but is alkylated on sulphur forming methylthiomethyl- and dimethylsulphonium methylide complexes.
T. J. Collins and W. R. Roper, J. Chem. Soc., Chem. Commun., 1977, 901 DOI: 10.1039/C39770000901
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