The unrearranged [14C]-AP·AP pyrromethane (2) is converted by deaminase–cosynthetase into uro'gen-III (7), thus supporting initial head-to-tail combination of porphobilinogen units for biosynthesis of the natural type-III porphyrins.
A. R. Battersby, D. G. Buckley, E. McDonald and D. C. Williams, J. Chem. Soc., Chem. Commun., 1977, 115 DOI: 10.1039/C39770000115
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