SCHEDULED MAINTENANCE
[OsHCl(CS)(PPh3)3] reacts with CO giving a blue thioformyl complex [Os(CHS)Cl(CO)2(PPh3)2]; this is readily methylated on sulphur forming a secondary thiocarbene complex which upon hydrolysis yields a formyl complex, [Os(CHO)Cl(CO)2(PPh3)2].
T. J. Collins and W. R. Roper, J. Chem. Soc., Chem. Commun., 1976, 1044 DOI: 10.1039/C39760001044
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