Issue 14, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel polynuclear cadmium complexes resulting from ring-opening reactions of 2,6-bis(2-r-2-benzoxazolinyl)pyridine (R = Me or H); X-ray structures of [Cd4(C21H17N3O2)2·(MeCO2)4]·Me2NCHO·H2O and [Cd3(C19H13N3O2)2·(MeCO2)2·(Me2NCHO)2]

David C. Liles,   Mary McPartlin,   Peter A. Tasker,   Hyacinth C. Lip  and  Leonard F. Lindoy  

Abstract

In solution the 2,6-bis(2-R-2-benzoxazolinyl)-pyridines (R = Me or H) undergo ring opening in the presence of Cd(MeCO2)2 to give unusual polynuclear complexes with very different structures; the differences may be attributed to steric interactions in the ligand with R = Me preventing this from adopting a near-planar configuration.

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Article information

DOI
https://doi.org/10.1039/C39760000549
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 549-551

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Novel polynuclear cadmium complexes resulting from ring-opening reactions of 2,6-bis(2-r-2-benzoxazolinyl)pyridine (R = Me or H); X-ray structures of [Cd4(C21H17N3O2)2·(MeCO2)4]·Me2NCHO·H2O and [Cd3(C19H13N3O2)2·(MeCO2)2·(Me2NCHO)2]

D. C. Liles, M. McPartlin, P. A. Tasker, H. C. Lip and L. F. Lindoy, J. Chem. Soc., Chem. Commun., 1976, 549 DOI: 10.1039/C39760000549

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