Issue 24, 1974

A pulsed-laser stimulated biphotonic photoreduction of hexa-amminecobalt(III)

Abstract

A photoredox process has been discovered in the 337 nm pulsed laser photolysis of Co(NH3)63+ which appears to involve two consecutive single photon absorptions; the process is accounted for by generation of a photoactive, charge-transfer state from absorption by a ligand-field excited state, and has considerable mechanistic significance.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 1024-1025

A pulsed-laser stimulated biphotonic photoreduction of hexa-amminecobalt(III)

K. M. Cunningham and J. F. Endicott, J. Chem. Soc., Chem. Commun., 1974, 1024 DOI: 10.1039/C39740001024

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