Issue 1, 1974

A new class of binuclear rhenium(II) halide species containing a strong metal–metal bond: the chemistry and structure of complexes of the type Re2X4(Pr3)4

Abstract

A new class of tertiary phosphine complexes of the type Re2Cl4(PR3)4 have been isolated from the reation of Re3Cl9 or the Re2Cl82– anion with the appropriate phosphine, and a single crystal X-ray structure analysis has shown Re2Cl4(PEt3)4 to posses a strong (evidently quadruple) rhenium–rhenium bond and eclipsed rotational configuration.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 4-5

A new class of binuclear rhenium(II) halide species containing a strong metal–metal bond: the chemistry and structure of complexes of the type Re2X4(Pr3)4

F. A. Cotton, B. A. Frenz, J. R. Ebner and R. A. Walton, J. Chem. Soc., Chem. Commun., 1974, 4 DOI: 10.1039/C39740000004

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements