Issue 22, 1973

Activated metals. The effect of added metal salts on magnesium reactivity

Abstract

Reduction of anhydrous magnesium chloride with potassium in refluxing THF in the presence of potassium iodide yields a black magnesium powder of exceptional reactivity, as demonstrated by its reaction with p-chlorotoluene, p-fluorotoluene, and other organic halides to give the corresponding Grignard reagents in high yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 879-880

Activated metals. The effect of added metal salts on magnesium reactivity

R. D. Rieke and S. E. Bales, J. Chem. Soc., Chem. Commun., 1973, 879 DOI: 10.1039/C39730000879

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