Equilibrium constants for the reversible dioxygen uptake by neutral cobalt(II) chelates with the same electronic structure show that the tendency to form dioxygen adducts increases with an increase in the ease of oxidation of cobalt(II) to cobalt(III), but on this basis vitamin B12r has a smaller tendency to add dioxygen than is expected.
M. J. Carter, L. M. Engelhardt, D. P. Rillema and F. Basolo, J. Chem. Soc., Chem. Commun., 1973, 810 DOI: 10.1039/C39730000810
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