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Reaction of excess of atomic lithium at 800–1000 °C with carbon tetrachloride and hexachloroethane produces tetralithiomethane and hexalithioethane, the first examples of perlithiated alkanes; the new compound tetralithioethylene is also produced in the first reaction.
C. Chung and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1972, 1078b DOI: 10.1039/C3972001078B
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