Issue 8, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Complex-forming reactions of an arylcopper(I) cluster compound with organophosphines. An unexpected C(alkyl)–P bond cleavage in 1,2-bis(diphenylphosphino)ethane

G. van Koten  and  J. G. Noltes  

Abstract

Whereas the 1 : 1 reaction of (2-cupriobenzyl)dimethylamine (RCu) with 1,2-bis(diphenylphosphino)ethane (diphos) affords the 1 : 1 complex RCu(diphos), 1 : 2 reaction results in cleavage of the C(alkyl)–P bond with formation of Ph2PCu(diphos)(solv), RH, and Ph2PCH = CH2.

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Article information

DOI
https://doi.org/10.1039/C39720000452
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 452-453

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Complex-forming reactions of an arylcopper(I) cluster compound with organophosphines. An unexpected C(alkyl)–P bond cleavage in 1,2-bis(diphenylphosphino)ethane

G. van Koten and J. G. Noltes, J. Chem. Soc., Chem. Commun., 1972, 452 DOI: 10.1039/C39720000452

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