Issue 34, 2012
From the journal:

Physical Chemistry Chemical Physics

Modular electron donor group tuning of frontier energy levels in diarylaminofluorenone push–pull molecules†

Paul J. Homnicka  and  Paul M. Lahti*a  

* Corresponding authors

a Department of Chemistry, University of Massachusetts, Amherst, USA
E-mail: lahti@chem.umass.edu
Tel: +1-413-545-2291

Abstract

Push–pull organic molecules composed of electron donor diarylamines at the 2- and 2,7-positions of fluorenone exhibit intramolecular charge-transfer behaviour in static absorption and emission spectra. Electrochemical and spectral data combined in a modular electronic analysis model show how the donor HOMO and acceptor LUMO act as major determinants of the frontier molecular orbital energy levels.

Graphical abstract: Modular electron donor group tuning of frontier energy levels in diarylaminofluorenone push–pull molecules

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CP41813D
Article type
Paper
Submitted
31 May 2012
Accepted
11 Jul 2012
First published
31 Jul 2012

Phys. Chem. Chem. Phys., 2012,14, 11961-11968

Permissions

Request permissions

Modular electron donor group tuning of frontier energy levels in diarylaminofluorenone push–pull molecules

P. J. Homnick and P. M. Lahti, Phys. Chem. Chem. Phys., 2012, 14, 11961 DOI: 10.1039/C2CP41813D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements