Feeding experiments with specifically and stereospecifically 14C- and 3H-labelled shikimic acids confirm earlier results in vitamin K and juglone formation and show that the biosynthesis involves loss of the pro-6R and retention of the pro-6S hydrogen of shikimate.
K.-H. Scharf, M. H. Zenk, D. K. Onderka, M. Carroll and H. G. Floss, J. Chem. Soc. D, 1971, 576 DOI: 10.1039/C29710000576
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