SCHEDULED MAINTENANCE
The rate constants for the ion-pair metatheses p-toluidinium toluene-p-sulphonate + metal acetate ⇌p-toluidinium acetate + metal toluene-p-sulphonate have been measured using an n.m.r. technique; the rate constants are ca. 109M–1 S–1 and show that the slow step in the exchange involves cation–acetate cleavage.
M. R. Crampton and E. Grunwald, J. Chem. Soc. D, 1970, 983 DOI: 10.1039/C29700000983
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