Issue 10, 2012

Flexible low-voltage organic thin-film transistors and circuits based on C10-DNTT

Abstract

Using the recently developed organic semiconductor, 2,9-didecyldinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophene (C10-DNTT), we have fabricated organic thin-film transistors and ring oscillators on flexible polymeric substrates. By utilizing a gate dielectric with a small thickness (5.3 nm) and a large capacitance (800 nF cm−2), the transistors can be operated with relatively low voltages of about 2 to 3 V. To improve the charge exchange between the organic semiconductor and the gold source and drain contacts, a thin layer of a non-alkylated organic semiconductor (DNTT) sandwiched between two thin layers of a strong organic dopant (NDP-9) was inserted between the C10-DNTT and the gold contacts. The optimized transistors have a field-effect mobility of 4.3 cm2 V−1 s−1, an on/off current ratio of 108, and a subthreshold swing of 68 mV per decade. The ring oscillators have a signal propagation delay of 5 μs per stage at a supply voltage of 3 V, making these the fastest organic circuits at supply voltages below 7 V reported to date.

Graphical abstract: Flexible low-voltage organic thin-film transistors and circuits based on C10-DNTT

Article information

Article type
Communication
Submitted
30 Sep 2011
Accepted
14 Nov 2011
First published
05 Dec 2011

J. Mater. Chem., 2012,22, 4273-4277

Flexible low-voltage organic thin-film transistors and circuits based on C10-DNTT

U. Zschieschang, M. J. Kang, K. Takimiya, T. Sekitani, T. Someya, T. W. Canzler, A. Werner, J. Blochwitz-Nimoth and H. Klauk, J. Mater. Chem., 2012, 22, 4273 DOI: 10.1039/C1JM14917B

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