Issue 38, 2011
From the journal:

Dalton Transactions

Construction of 1-D 4f and 3d–4f coordination polymers with flexible Schiff base ligands†

Xiaoping Yang,a   Daniel Lam,a   Christopher Chan,a   Julie M. Stanley,a   Richard A. Jones,*a   Bradley J. Holliday*a  and  Wai-Kwok Wong*b  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station, Austin, TX, USA
E-mail: rajones@mail.utexas.edu, bholliday@cm.utexas.edu

b Department of Chemistry and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, China
E-mail: wkwong@hkbu.edu.hk

Abstract

Three new lanthanide 1-D coordination polymers ({[Ln2(H2L)(OAc)6]·EtOH·2H2O}n (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc)2(H2O)}n (3)) and a heterobinuclear complex [YbNiLCl3(H2O)3] (4) are reported which are formed from salen type Schiff-base ligands H2L (H2L = N,N′-bis(3-methoxysalicylidene)butane-1,4-diamine). The polymeric structures are formed by bridging H2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1–4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.

Graphical abstract: Construction of 1-D 4f and 3d–4f coordination polymers with flexible Schiff base ligands

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Article information

DOI
https://doi.org/10.1039/C1DT11036E
Article type
Paper
Submitted
03 Jun 2011
Accepted
27 Jul 2011
First published
26 Aug 2011

Dalton Trans., 2011,40, 9795-9801

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Construction of 1-D 4f and 3d–4f coordination polymers with flexible Schiff base ligands

X. Yang, D. Lam, C. Chan, J. M. Stanley, R. A. Jones, B. J. Holliday and W. Wong, Dalton Trans., 2011, 40, 9795 DOI: 10.1039/C1DT11036E

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