Issue 11, 2012

Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs+-based half SOD β-cage

Abstract

In light of ever growing interests in noncentrosymmetric materials, a fascinating reticular chemistry is illustrated via the structure of a new family of solids where the acentric symmetry of the well-known [V4+14As3+8O42Cl]5POM cluster is manifested through the network construction of counter cations featuring slabs of Cs+-based half SOD β-cages.

Graphical abstract: Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs+-based half SOD β-cage

Supplementary files

Article information

Article type
Communication
Submitted
08 Oct 2011
Accepted
11 Nov 2011
First published
14 Nov 2011

Chem. Commun., 2012,48, 1665-1667

Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs+-based half SOD β-cage

W. L. Queen, J. P. West, S. Hwu, T. T. Tran, P. S. Halasyamani and D. VanDerveer, Chem. Commun., 2012, 48, 1665 DOI: 10.1039/C1CC16264K

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