Issue 1, 2012

Melting point suppression in new lanthanoid(iii) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study

Abstract

The complexes (N4444)3[Ln(dcnm)6] (Ln = La–Nd, Sm; N4444 = tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situsynchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.

Graphical abstract: Melting point suppression in new lanthanoid(iii) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2011
Accepted
05 Oct 2011
First published
03 Nov 2011

Chem. Commun., 2012,48, 124-126

Melting point suppression in new lanthanoid(III) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study

A. S. R. Chesman, M. Yang, B. Mallick, T. M. Ross, I. A. Gass, G. B. Deacon, S. R. Batten and A. Mudring, Chem. Commun., 2012, 48, 124 DOI: 10.1039/C1CC14744G

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