Issue 31, 2011
From the journal:

Chemical Communications

Homoleptic ruthenium(iii) chalcogenolates: a single precursor to metal chalcogenide nanoparticles catalyst†

Sharon Lai-Fung Chan,a   Kam-Hung Low,a   Gary Kwok-Ming So,a   Stephen Sin-Yin Chuia  and  Chi-Ming Che*a  

* Corresponding authors

a Department of Chemistry, State Key Laboratory of Synthetic Chemistry, and Institute of Molecular Functional Materials, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, China
E-mail: cmche@hku.hk
Fax: 852 2857 1586
Tel: 852 2859 2154

Abstract

Eight homoleptic metal(III) arylchalcogenolate polymers [M(EPh-p-X)3]n (M = Ru, Cr, and Mo) were characterized by PXRD. Structural solution of [Ru(SPh-p-tBu)3]n1 was achieved by Rietveld refinement of the PXRD data. Pyrolysis of [Ru(SePh)3]n4 produced nanostructured RuSe2, which selectively catalyzed the reduction of nitro compounds in the presence of other functionalities.

Graphical abstract: Homoleptic ruthenium(iii) chalcogenolates: a single precursor to metal chalcogenide nanoparticles catalyst

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC12422F
Article type
Communication
Submitted
26 Apr 2011
Accepted
21 Jun 2011
First published
07 Jul 2011

Chem. Commun., 2011,47, 8808-8810

Permissions

Request permissions

Homoleptic ruthenium(III) chalcogenolates: a single precursor to metal chalcogenide nanoparticles catalyst

S. L. Chan, K. Low, G. K. So, S. S. Chui and C. Che, Chem. Commun., 2011, 47, 8808 DOI: 10.1039/C1CC12422F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements