Issue 15, 2011

Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion

Abstract

Hydrogen bond induced reactivity and selectivity control in the 1-butyl-3-methylimidazolium based ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds is reported with remarkable influence of the anion and the C-2 hydrogen in catalytic activity and reversal of selectivity.

Graphical abstract: Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion

Supplementary files

Article information

Article type
Communication
Submitted
08 Jan 2011
Accepted
21 Feb 2011
First published
09 Mar 2011

Chem. Commun., 2011,47, 4538-4540

Ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds—remarkable influence of the C-2 hydrogen and the anion

A. Sarkar, S. R. Roy and A. K. Chakraborti, Chem. Commun., 2011, 47, 4538 DOI: 10.1039/C1CC10151J

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