Issue 2, 2011

In(iii)-pybox complex catalyzed enantioselective Mukaiyama aldol reactions between polymeric or hydrated glyoxylates and enolsilanes derived from aryl ketones

Abstract

A highly efficient In(III)-pybox complex catalyzed enantio-selective Mukaiyama aldol reaction between polymeric or hydrated glyoxylates and enolsilanes derived from aryl ketones is described. Excellent enantioselectivities, diastereoselectivities and yields were obtained with a broad substrate scope. The mild reaction conditions and simple operation make this methodology very practical.

Graphical abstract: In(iii)-pybox complex catalyzed enantioselective Mukaiyama aldol reactions between polymeric or hydrated glyoxylates and enolsilanes derived from aryl ketones

Supplementary files

Article information

Article type
Edge Article
Submitted
22 Aug 2010
Accepted
20 Sep 2010
First published
28 Oct 2010

Chem. Sci., 2011,2, 349-352

In(III)-pybox complex catalyzed enantioselective Mukaiyama aldol reactions between polymeric or hydrated glyoxylates and enolsilanes derived from aryl ketones

J. Zhao, B. Tan and T. Loh, Chem. Sci., 2011, 2, 349 DOI: 10.1039/C0SC00454E

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