Issue 46, 2010
From the journal:

Dalton Transactions

Magnesium hydride-promoted dearomatisation of pyridine†

Michael S. Hill,*a   Dugald J. MacDougalla  and  Mary F. Mahona  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: msh27@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 383394

Abstract

Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.

Graphical abstract: Magnesium hydride-promoted dearomatisation of pyridine

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Article information

DOI
https://doi.org/10.1039/C0DT01246G
Article type
Communication
Submitted
16 Sep 2010
Accepted
04 Oct 2010
First published
20 Oct 2010

Dalton Trans., 2010,39, 11129-11131

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Magnesium hydride-promoted dearomatisation of pyridine

M. S. Hill, D. J. MacDougall and M. F. Mahon, Dalton Trans., 2010, 39, 11129 DOI: 10.1039/C0DT01246G

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