Issue 2, 2011

A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent FeIII h.s.(μ-O)2FeIV h.s. species

Abstract

The design and first application of a new dinucleating ligand system to mimic high-valent oxidation states of O2-dependent diiron enzymes is presented.

Graphical abstract: A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent FeIII h.s.(μ-O)2FeIV h.s. species

Supplementary files

Article information

Article type
Communication
Submitted
06 Aug 2010
Accepted
25 Oct 2010
First published
19 Nov 2010

Chem. Commun., 2011,47, 695-697

A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent FeIII h.s.(μ-O)2FeIV h.s. species

J. B. H. Strautmann, S. Walleck, H. Bögge, A. Stammler and T. Glaser, Chem. Commun., 2011, 47, 695 DOI: 10.1039/C0CC03098H

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