Issue 1, 2011
From the journal:

Chemical Communications

Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides†‡

Mason A. Stewart,a   Curtis E. Moore,a   Treffly B. Ditri,a   Liezel A. Labios,a   Arnold L. Rheingolda  and  Joshua S. Figueroa*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, USA
E-mail: jsfig@ucsd.edu
Fax: +1 858 822-4446

Abstract

The m-terphenyl isocyanides CNArMes2 and CNArDipp2 support five-coordinate, isocyanide/carbonyl monoanions of manganese. For CNArDipp2, a bis-isocyanide anion is available that is remarkably well behaved upon reaction with electrophiles. Most notable is the formation of an unprecedented chloride-substituted metallostannylene.

Graphical abstract: Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides

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Article information

DOI
https://doi.org/10.1039/C0CC02742A
Article type
Communication
Submitted
23 Jul 2010
Accepted
24 Aug 2010
First published
17 Sep 2010

Chem. Commun., 2011,47, 406-408

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Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides

M. A. Stewart, C. E. Moore, T. B. Ditri, L. A. Labios, A. L. Rheingold and J. S. Figueroa, Chem. Commun., 2011, 47, 406 DOI: 10.1039/C0CC02742A

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