Issue 7, 2010

Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes

Abstract

New Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne and 1-allene-vinylcyclopropanes have been developed, affording an efficient and versatile synthesis of cyclopentane- and cyclopentene-embedded bicyclic structures.

Graphical abstract: Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes

Supplementary files

Article information

Article type
Communication
Submitted
26 Oct 2009
Accepted
18 Nov 2009
First published
14 Dec 2009

Chem. Commun., 2010,46, 1059-1061

Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes

L. Jiao, M. Lin and Z. Yu, Chem. Commun., 2010, 46, 1059 DOI: 10.1039/B922417C

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