Issue 14, 2010
From the journal:

Dalton Transactions

Resin-assisted solvothermal synthesis of transition metal–organic frameworks†

Yi Du,a   Amber L. Thompson,a   Nicola Russella  and  Dermot O'Hare*a  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: dermot.ohare@chem.ox.ac.uk
Fax: 44-1865-272690
Tel: 44-1865-272686

Abstract

Cation-exchanged polymer resin beads have been used as a heterogeneous controlled-release source of metal cations in phase pure and/or high yielding solvothermal syntheses of novel transition metal–organic frameworks. The introduction of the resin beads has a dramatic effect on the outcome of solvothermal reactions. We report the syntheses of a series of transition metal-containing MOFs via the resin-assisted solvothermal methods, four novel MOFs are reported that could not be synthesised by traditional methods. These MOFs have been characterized using elemental analysis, powder XRD, single crystal XRD, FESEM, EPR, B.E.T. surface analysis, and solid state magnetic measurements.

Graphical abstract: Resin-assisted solvothermal synthesis of transition metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/B919675G
Article type
Paper
Submitted
21 Sep 2009
Accepted
04 Jan 2010
First published
23 Feb 2010

Dalton Trans., 2010,39, 3384-3395

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Resin-assisted solvothermal synthesis of transition metal–organic frameworks

Y. Du, A. L. Thompson, N. Russell and D. O'Hare, Dalton Trans., 2010, 39, 3384 DOI: 10.1039/B919675G

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