Issue 41, 2009
From the journal:

Dalton Transactions

Transformation of polymerization of polar vinyl monomers by discrete and hybrid metal catalysts

Eugene Y.-X. Chen*a  

* Corresponding authors

a Department of Chemistry, Colorado State University, Fort Collins, Colorado, USA
E-mail: eugene.chen@colostate.edu
Tel: +1 970 491 5609

Abstract

Chiral metallocene cations, discrete main group anions, dually active ion pairs and nucleophile/electrophile pairs have been utilized to transform the polymerization of polar vinyl monomers from one type to another. These discrete or hybrid catalysts have enabled the development of five types of such polymerizations, including stereospecific and living coordination polymerization, asymmetric coordination polymerization, single-site anionic polymerization, bimolecular polymer-transfer polymerization, and diastereospecific ion-pairing polymerization.

Graphical abstract: Transformation of polymerization of polar vinyl monomers by discrete and hybrid metal catalysts

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Article information

DOI
https://doi.org/10.1039/B912640F
Article type
Perspective
Submitted
26 Jun 2009
Accepted
16 Jul 2009
First published
21 Aug 2009

Dalton Trans., 2009, 8784-8793

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Transformation of polymerization of polar vinyl monomers by discrete and hybrid metal catalysts

E. Y.-X. Chen, Dalton Trans., 2009, 8784 DOI: 10.1039/B912640F

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