Issue 35, 2009
From the journal:

Dalton Transactions

Unprecedented cubane-type silvercluster with a novel phosphinite functionalized N-heterocyclic carbene ligand†

Matthieu Raynal,a   Xianghao Liu,a   Roberto Pattacini,a   Christophe Vallée,b   Hélène Olivier-Bourbigoub  and  Pierre Braunstein*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination, Institut de Chimie, UMR 7177 CNRS, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg Cedex, France
E-mail: braunstein@chimie.u-strasbg.fr
Fax: +33 390 241 322

b IFP-Lyon, Rond Point de l'Echangeur de Solaize, BP3, France

Abstract

A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag2I2 faces.

Graphical abstract: Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B911439D
Article type
Paper
Submitted
11 Jun 2009
Accepted
16 Jul 2009
First published
04 Aug 2009

Dalton Trans., 2009, 7288-7293

Permissions

Request permissions

Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

M. Raynal, X. Liu, R. Pattacini, C. Vallée, H. Olivier-Bourbigou and P. Braunstein, Dalton Trans., 2009, 7288 DOI: 10.1039/B911439D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements