Issue 36, 2009

Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Abstract

Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage.

Graphical abstract: Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Supplementary files

Article information

Article type
Communication
Submitted
10 Jun 2009
Accepted
04 Aug 2009
First published
14 Aug 2009

Chem. Commun., 2009, 5403-5405

Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

P. D. Abram, D. Ellis, G. M. Rosair and A. J. Welch, Chem. Commun., 2009, 5403 DOI: 10.1039/B911350A

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