Issue 25, 2009

Bio-inspired polyenecyclization: aziridinyl polyenecyclization catalyzed by InBr3

Abstract

This communication describes a highly efficient aziridinyl polyolefin cyclization catalyzed by InBr3 to synthesize chiral terpenoid bearing a 3-amino group in the A ring; both good yields and excellent asymmetric induction were achieved.

Graphical abstract: Bio-inspired polyenecyclization: aziridinyl polyenecyclization catalyzed by InBr3

Supplementary files

Article information

Article type
Communication
Submitted
23 Feb 2009
Accepted
21 Apr 2009
First published
18 May 2009

Chem. Commun., 2009, 3738-3740

Bio-inspired polyenecyclization: aziridinyl polyenecyclization catalyzed by InBr3

Y. Zhao, L. S. Tan, B. Li, S. Li and T. Loh, Chem. Commun., 2009, 3738 DOI: 10.1039/B903696B

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