AgOC(CF3)3: an alternative and efficient reagent for preparing transition metal-NHC-carbene complexes

Tarun Kumar Maishal; Jean-Marie Basset; Malika Boualleg; Christophe Copéret; Laurent Veyre; Chloé Thieuleux

doi:10.1039/B900136K

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AgOC(CF₃)₃: an alternative and efficient reagent for preparing transition metal-NHC-carbene complexes†

Tarun Kumar Maishal,^a Jean-Marie Basset,^a Malika Boualleg,^a Christophe Copéret,^a Laurent Veyre^a and Chloé Thieuleux*^a

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* Corresponding authors

^a Université de Lyon, Institut de Chimie de Lyon, C2P2-Equipe COMS (UMR 5265 CNRS-CPE Lyon-Université de Lyon 1), CPE Lyon, 43 Bd du 11 Novembre 1918, Villeurbanne Cedex, France
E-mail: thieuleux@cpe.fr
Fax: +33 (0) 472431795
Tel: +33 (0) 472431799

Abstract

AgOC(CF₃)₃, a soluble source, was found to be a convenient reagent for the one-pot preparation of Ag-NHC and M-NHC complexes starting from imidazoliums (M = Au, Ir, Pd and Ru).

This article is part of the themed collection: N-heterocyclic carbenes

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Supplementary files

¹H and ¹³C NMR spectra PDF (634K)

Article information

DOI: https://doi.org/10.1039/B900136K
Article type: Paper
Submitted: 06 Jan 2009
Accepted: 24 Apr 2009
First published: 08 Jun 2009

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Dalton Trans., 2009, 6956-6959

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AgOC(CF₃)₃: an alternative and efficient reagent for preparing transition metal-NHC-carbene complexes

T. K. Maishal, J. Basset, M. Boualleg, C. Copéret, L. Veyre and C. Thieuleux, Dalton Trans., 2009, 6956 DOI: 10.1039/B900136K

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Dalton Transactions