Homochiral moganite-type metal–organic framework based on unusual (Ag2Cl)n skeletons

Lei Zhang; Zhao-Ji Li; Ye-Yan Qin; Jian Zhang; Jian-Kai Cheng; Pei-Xiu Yin; Yuan-Gen Yao

doi:10.1039/B801310A

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Homochiral moganite-type metal–organic framework based on unusual (Ag₂Cl)_n skeletons†‡§

Lei Zhang,^ab Zhao-Ji Li,^a Ye-Yan Qin,^a Jian Zhang,^a Jian-Kai Cheng,^a Pei-Xiu Yin^ab and Yuan-Gen Yao*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, China
E-mail: yyg@fjirsm.ac.cn
Fax: +86-591-8371-4946
Tel: +86-591-8371-1523

^b Graduate School of The Chinese Academy of Sciences, Beijing, China

Abstract

A homochiral hybrid organic/inorganic material {[Ag₂(4,4′-bipy)₂Cl]·(NO₃)}_n (1, 4,4′-bipy = 4,4′-bipyridine), with unusual moganite topology, has been constructed by 4,4′-bipy combining argentum halide skeletons, which are formed based on the unprecedented planar μ₄-bridging Cl.

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Article information

DOI: https://doi.org/10.1039/B801310A
Article type: Communication
Submitted: 24 Jan 2008
Accepted: 25 Feb 2008
First published: 14 Mar 2008

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CrystEngComm, 2008,10, 655-657

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Homochiral moganite-type metal–organic framework based on unusual (Ag₂Cl)_n skeletons

L. Zhang, Z. Li, Y. Qin, J. Zhang, J. Cheng, P. Yin and Y. Yao, CrystEngComm, 2008, 10, 655 DOI: 10.1039/B801310A

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