Issue 19, 2008
From the journal:

Chemical Communications

Reversible shrinkage and expansion of a blue photofluorescent cadmium coordination polymer and in situtetrazole ligand synthesis†

Hong Deng,*a   Yong-Cai Qiu,a   Ying-Hua Li,a   Zhi-Hui Liu,a   Rong-Hua Zeng,a   Matthias Zellerb  and  Stuart R. Battenc  

* Corresponding authors

a School of Chemistry & Environment, South China Normal University, Guangzhou, P. R. China
E-mail: dh@scnu.edu.cn
Fax: +862039310187
Tel: +862033381880

b Youngstown State University, Department of Chemistry, One University Plaza, Youngstown, Ohio 44555-3663, USA

c School of Chemistry, Monash University, Victoria 3800, Australia

Abstract

The metal–organic framework [Cd15(5MT)18(OH)4(SO4)4] (5-MT = 5-methyl-1H-tetrazole) with an unprecedented Cd3(μ3-OH)(μ3-SO4) core and two kinds of tetrazole coordination modes was formed by self-assembly and in situ synthesis of the 5-MT tetrazole ligand; the structure exhibits an unusual 39·412·515 topological network and shows reversible shrinkage and expansion in a crystal-to-crystal dehydration/rehydration process.

Graphical abstract: Reversible shrinkage and expansion of a blue photofluorescent cadmium coordination polymer and in situtetrazole ligand synthesis

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Article information

DOI
https://doi.org/10.1039/B800938D
Article type
Communication
Submitted
18 Jan 2008
Accepted
20 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 2239-2241

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Reversible shrinkage and expansion of a blue photofluorescent cadmium coordination polymer and in situtetrazole ligand synthesis

H. Deng, Y. Qiu, Y. Li, Z. Liu, R. Zeng, M. Zeller and S. R. Batten, Chem. Commun., 2008, 2239 DOI: 10.1039/B800938D

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