Issue 22, 2008

Organically templated metal–organic framework with 2-fold interpenetrated {33.59.63}-lcy net

Abstract

A new organic cation templated Zn(II) complex (Et3NH)[Zn4(ip)3(bta)3] (1, ip = isophthalate, Hbta = benzotriazole) which consists of plate-like Zn4(bta)3 units bridged by ip ligands is reported; it is the first example of a 6-connected uninodal {33.59.63}-lcy net which has never been observed previously in MOFs but has been theoretically anticipated.

Graphical abstract: Organically templated metal–organic framework with 2-fold interpenetrated {33.59.63}-lcy net

Supplementary files

Article information

Article type
Communication
Submitted
03 Jan 2008
Accepted
26 Feb 2008
First published
28 Mar 2008

Chem. Commun., 2008, 2532-2534

Organically templated metal–organic framework with 2-fold interpenetrated {33.59.63}-lcy net

Y. Qin, J. Zhang, Z. Li, L. Zhang, X. Cao and Y. Yao, Chem. Commun., 2008, 2532 DOI: 10.1039/B800017D

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