Issue 13, 2008
From the journal:

Chemical Communications

Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of α,ω-diynes†

Vincent Gandon,ab   Corinne Aubert,b   Max Malacriab  and  K. Peter C. Vollhardt*a  

* Corresponding authors

a Department of Chemistry, University of California at Berkeley, and the Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
E-mail: kpcv@berkeley.edu
Fax: ++1 510 643 5208
Tel: ++1 510 642 0286

b Laboratoire de Chimie Organique UMR 7611, Institut de Chimie Moléculaire FR2769, Université Pierre et Marie Curie, Tour 44-54, Paris, France

Abstract

In the presence of CpCo(C2H4)2, α,ω-diynes undergo hydroaminative coupling with amides to furnish new dienamides with control of regio- and stereochemistry.

Graphical abstract: Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of α,ω-diynes

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Article information

DOI
https://doi.org/10.1039/B716841A
Article type
Communication
Submitted
31 Oct 2007
Accepted
15 Jan 2008
First published
27 Feb 2008

Chem. Commun., 2008, 1599-1601

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Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of α,ω-diynes

V. Gandon, C. Aubert, M. Malacria and K. P. C. Vollhardt, Chem. Commun., 2008, 1599 DOI: 10.1039/B716841A

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