Abstract
The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C–O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.
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Goto, A., Scaiano, J.C. & Maretti, L. Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization. Photochem Photobiol Sci 6, 833–835 (2007). https://doi.org/10.1039/b705671k
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DOI: https://doi.org/10.1039/b705671k